Material Compatibility of Common Aerospace Metals in MMH/MON-3

This article is from the 2024 Technical Update.

The NESC evaluated material compatibility of some common aerospace metals in monomethylhydrazine (MMH) and nitrogen tetroxide (MON-3). Previous work had identified a lack of quantitative compatibility data for nickel alloy 718, 300 series stainless steel, and titanium Ti-6Al-4V in MMH and MON-3 to support the use of zero-failure-tolerant, thin-walled pressure barriers in these propellants. Static (i.e., not flowing) general corrosion and electrochemistry testing was conducted, evaluating varied processing forms and heat treatment of the metals, water content of propellant, and exposure duration. Corrosion-rate data for all tested product forms, fluids, and durations were on the order of 1 x 10–6 inch per year rather than the previously documented “less than 1 x 10–3 inch per year”. The majority of the corrosion products were seen in the first 20 days of exposure, with an overall corrosion rate decreasing with time due to the increased divisor (time). It is therefore recommended that corrosion testing be performed at multiple short-term durations to inform the need for longer-duration testing.

Background
Nickel alloy 718, 300 series stainless steel, and Ti-6Al-4V are commonly used in storable propulsion systems (i.e., MMH/MON-3), but a concern was raised regarding what quantitative compatibility data were available for proposed zero-failure-tolerant, thin-walled (~0.005 to 0.010 inch thickness) pressure barrier designs. A literature search found that limited and conflicting data were available for commonly used aerospace metals in MMH and MON-3. For example, corrosion behavior was listed qualitatively (e.g., “A” rating), data on materials and fluids tested were imprecise, fluids were identified as contaminated without describing how they were contaminated, no compatibility data were found on relevant geometry specimens (i.e., very thin-walled or convoluted), and limited data were available to quantify differences between tested materials and flight components. When corrosion data were quantified, documented sensitivity was “1 x 10–3 inch per year or less”, which is insufficient for assessing long-duration, thin-walled, flight-weight applications.

Discussion
General corrosion testing was performed with a static/non-flowing configuration based on NASA-STD-6001, Test 15 [1]. Design of experiments methods were used to develop a test matrix varying material, propellant, propellant water content, and tested duration. Materials tested were nickel alloy 718 (solution annealed sheet, aged sheet, aged/welded sheet, and hydroformed bellows), 300 series stainless steel (low carbon sheet, titanium stabilized sheet, and hydroformed bellows), and Ti 6Al-4V sheet. Samples were tested in sealed test tubes in MMH and MON-3 with water content ranging from as-received (“dry”) up to specification allowable limits [2,3]. Tested durations ranged from 20 to 365 days. Measurements included inductively coupled plasma mass spectrometry (ICPMS) to identify corrosion products and their concentrations in test fluid, gravimetric (i.e., scale) measurements pre- and post-exposure, and visual inspection. Bimetallic pairs (titanium stabilized 300 series stainless steel: Ti 6Al-4V and nickel alloy 718: Ti 6Al-4V) were tested for up to 65 days in both MMH and MON-3. The test setup incorporated important features of the test standard (e.g., electrode spacing and finish) and adapted the configuration for MMH/MON-3 operation. Measurements included potential difference and current flow between samples. Figure 1 shows images of the general corrosion and bimetallic pair test setups.

Test Results
For all tested materials and product forms, corrosion rates were on the order of 1 x 10–6 inch per year in MMH or MON-3, three orders of magnitude lower than historically reported. Corrosion products were generated in the first 20 days of exposure, and corrosion rate decreased with time due to the increase in divisor (i.e., time). Corrosion products increased as the water content of the propellants increased but remained in the same order of magnitude between the as-received dry propellant and propellant containing the maximum water content allowed by specification. Figure 2 illustrates test results for corrosion rate, mass loss with duration, and mass loss with water content. It is important to note that water has been demonstrated to contribute to flow decay even when water is within the specification allowable limit, and previous NASA-STD-6001 Test 15 data have demonstrated susceptibility of some nickel alloys to crevice-type corrosion attack [4]. Therefore, these results do not reduce the importance of considering the system impact of water content and evaluating for crevice corrosion behavior. Finally, in the bimetallic pair testing, tested materials did not measurably corrode in MON-3 and MMH within specification-allowable water content, as evidenced by no visual indications of corrosion and very low electrical interaction (i.e., corrosion rates derived to be less than 1 microinch per year from electrical interaction).

Recommendations
It is recommended that corrosion testing be performed at multiple shortterm durations to inform the need for longer-duration testing.

References

1. NASA-STD-6001 Flammability, Odor, Offgassing, and Compatibility Requirements
   and Test Procedures for Materials In Environments that Support Combustion
2. MIL-PRF-27404 Performance Specification: Propellant, Monomethylhydrazine
3. MIL-PRF-26539 Performance Specification: Propellants, Dinitrogen Tetroxide
4. WSTF Test 15 Report 12-45708 and WSTF Test 15 Report 13-46207

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Meagan Chappell

NASA’s Juno Mission Uncovers Heart of Jovian Moon’s Volcanic Rage

A new study points to why, and how, Io became the most volcanic body in the solar system.

Scientists with NASA’s Juno mission to Jupiter have discovered that the volcanoes on Jupiter’s moon Io are each likely powered by their own chamber of roiling hot magma rather than an ocean of magma. The finding solves a 44-year-old mystery about the subsurface origins of the moon’s most demonstrative geologic features.

A paper on the source of Io’s volcanism was published on Thursday, Dec. 12, in the journal Nature, and the findings, as well as other Io science results, were discussed during a media briefing in Washington at the American Geophysical Union’s annual meeting, the country’s largest gathering of Earth and space scientists.

About the size of Earth’s Moon, Io is known as the most volcanically active body in our solar system. The moon is home to an estimated 400 volcanoes, which blast lava and plumes in seemingly continuous eruptions that contribute to the coating on its surface. 

Although the moon was discovered by Galileo Galilei on Jan. 8, 1610, volcanic activity there wasn’t discovered until 1979, when imaging scientist Linda Morabito of NASA’s Jet Propulsion Laboratory in Southern California first identified a volcanic plume in an image from the agency’s Voyager 1 spacecraft.

“Since Morabito’s discovery, planetary scientists have wondered how the volcanoes were fed from the lava underneath the surface,” said Scott Bolton, Juno principal investigator from the Southwest Research Institute in San Antonio. “Was there a shallow ocean of white-hot magma fueling the volcanoes, or was their source more localized? We knew data from Juno’s two very close flybys could give us some insights on how this tortured moon actually worked.”

The Juno spacecraft made extremely close flybys of Io in December 2023 and February 2024, getting within about 930 miles (1,500 kilometers) of its pizza-faced surface. During the close approaches, Juno communicated with NASA’s Deep Space Network, acquiring high-precision, dual-frequency Doppler data, which was used to measure Io’s gravity by tracking how it affected the spacecraft’s acceleration. What the mission learned about the moon’s gravity from those flybys led to the new paper by revealing more details about the effects of a phenomenon called tidal flexing.

Prince of Jovian Tides

Io is extremely close to mammoth Jupiter, and its elliptical orbit whips it around the gas giant once every 42.5 hours. As the distance varies, so does Jupiter’s gravitational pull, which leads to the moon being relentlessly squeezed. The result: an extreme case of tidal flexing — friction from tidal forces that generates internal heat.

“This constant flexing creates immense energy, which literally melts portions of Io’s interior,” said Bolton. “If Io has a global magma ocean, we knew the signature of its tidal deformation would be much larger than a more rigid, mostly solid interior. Thus, depending on the results from Juno’s probing of Io’s gravity field, we would be able to tell if a global magma ocean was hiding beneath its surface.”

The Juno team compared Doppler data from their two flybys with observations from the agency’s previous missions to the Jovian system and from ground telescopes. They found tidal deformation consistent with Io not having a shallow global magma ocean.

“Juno’s discovery that tidal forces do not always create global magma oceans does more than prompt us to rethink what we know about Io’s interior,” said lead author Ryan Park, a Juno co-investigator and supervisor of the Solar System Dynamics Group at JPL. “It has implications for our understanding of other moons, such as Enceladus and Europa, and even exoplanets and super-Earths. Our new findings provide an opportunity to rethink what we know about planetary formation and evolution.”

There’s more science on the horizon. The spacecraft made its 66^th science flyby over Jupiter’s mysterious cloud tops on Nov. 24. Its next close approach to the gas giant will occur 12:22 a.m. EST, Dec. 27. At the time of perijove, when Juno’s orbit is closest to the planet’s center, the spacecraft will be about 2,175 miles (3,500 kilometers) above Jupiter’s cloud tops and will have logged 645.7 million miles (1.039 billion kilometers) since entering the gas giant’s orbit in 2016.

More About Juno

JPL, a division of Caltech in Pasadena, California, manages the Juno mission for the principal investigator, Scott Bolton, of the Southwest Research Institute in San Antonio. Juno is part of NASA’s New Frontiers Program, which is managed at NASA’s Marshall Space Flight Center in Huntsville, Alabama, for the agency’s Science Mission Directorate in Washington. The Italian Space Agency (ASI) funded the Jovian InfraRed Auroral Mapper. Lockheed Martin Space in Denver built and operates the spacecraft. Various other institutions around the U.S. provided several of the other scientific instruments on Juno.

More information about Juno is available at:

https://science.nasa.gov/mission/juno

News Media Contacts

DC Agle
Jet Propulsion Laboratory, Pasadena, Calif.
818-393-9011
agle@jpl.nasa.gov

Karen Fox / Erin Morton
NASA Headquarters, Washington
202-385-1287 / 202-805-9393
karen.c.fox@nasa.gov / erin.morton@nasa.gov

Deb Schmid
Southwest Research Institute, San Antonio
210-522-2254
dschmid@swri.org

2024-173

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NASA Successfully Integrates Roman Mission’s Telescope, Instruments

NASA’s Nancy Grace Roman Space Telescope team has successfully integrated the mission’s telescope and two instruments onto the instrument carrier, marking the completion of the Roman payload. Now the team at NASA’s Goddard Space Flight Center in Greenbelt, Maryland, will begin joining the payload to the spacecraft.

“We’re in the middle of an exciting stage of mission preparation,” said Jody Dawson, a Roman systems engineer at NASA Goddard. “All the components are now here at Goddard, and they’re coming together in quick succession. We expect to integrate the telescope and instruments with the spacecraft before the year is up.”

Engineers first integrated the Coronagraph Instrument, a technology demonstration designed to image exoplanets — worlds outside our solar system — by using a complex suite of masks and active mirrors to obscure the glare of the planets’ host stars.

Then the team integrated the Optical Telescope Assembly, which includes a 7.9-foot (2.4-meter) primary mirror, nine additional mirrors, and their supporting structures and electronics. The telescope will focus cosmic light and send it to Roman’s instruments, revealing billions of objects strewn throughout space and time. Roman will be the most stable large telescope ever built, at least 10 times more so than NASA’s James Webb Space Telescope and 100 times more than the agency’s Hubble Space Telescope. This will allow scientists to make measurements at levels of precision that can answer important questions about dark energy, dark matter, and worlds beyond our solar system.

With those components in place, the team then added Roman’s primary instrument. Called the Wide Field Instrument, this 300-megapixel infrared camera will give Roman a deep, panoramic view of the universe. Through the Wide Field Instrument’s surveys, scientists will be able to explore distant exoplanets, stars, galaxies, black holes, dark energy, dark matter, and more. Thanks to this instrument and the observatory’s efficiency, Roman will be able to image large areas of the sky 1,000 times faster than Hubble with the same sharp, sensitive image quality.

“It would be quicker to list the astronomy topics Roman won’t be able to address than those it will,” said Julie McEnery, the Roman senior project scientist at NASA Goddard. “We’ve never had a tool like this before. Roman will revolutionize the way we do astronomy.”

The telescope and instruments were mounted to Roman’s instrument carrier and precisely aligned in the largest clean room at Goddard, where the observatory is being assembled. Now, the whole assembly is being attached to the Roman spacecraft, which will deliver the observatory to its orbit and enable it to function once there.

At the same time, the mission’s deployable aperture cover — a visor that will shield the telescope from unwanted light — is being joined to the outer barrel assembly, which serves as the telescope’s exoskeleton.

“We’ve had an incredible year, and we’re looking forward to another one!” said Bear Witherspoon, a Roman systems engineer at NASA Goddard. “While the payload and spacecraft undergo a smattering of testing together, the team will work toward integrating the solar panels onto the outer barrel assembly.”

That keeps the observatory on track for completion by fall 2026 and launch no later than May 2027.

To virtually tour an interactive version of the telescope, visit:

https://roman.gsfc.nasa.gov/interactive

The Nancy Grace Roman Space Telescope is managed at NASA’s Goddard Space Flight Center in Greenbelt, Maryland, with participation by NASA’s Jet Propulsion Laboratory and Caltech/IPAC in Southern California, the Space Telescope Science Institute in Baltimore, and a science team comprising scientists from various research institutions. The primary industrial partners are BAE Systems Inc. in Boulder, Colorado; L3Harris Technologies in Rochester, New York; and Teledyne Scientific & Imaging in Thousand Oaks, California.

By Ashley Balzer
NASA’s Goddard Space Flight Center, Greenbelt, Md.

​​Media Contact:

Claire Andreoli
NASA’s Goddard Space Flight Center
301-286-1940

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Sols 4389-4390: A Wealth of Ripples, Nodules and Veins

Earth planning date: Monday, Dec. 9, 2024

We are continuing to edge our way around the large “Texoli” butte. Much of the bedrock we have been traversing recently looks pretty similar — paler-colored laminated bedrock — but today’s workspace had some interesting features, as did the “drive direction” image, which focuses on the future drive path.

Close to the rover, we had a wealth of fractures and darker-toned patches. The fractures or veins were too far from the rover for contact science, but ChemCam LIBS was able to target one of the more prominent ones at “Garlock Fault.” Luckily for the contact science instruments (APXS and MAHLI), the darker patches were within reach of the arm. Some of the darker patches were flatter and platy in appearance, whilst others had a more amorphous, blobby shape. Both types come with their own challenges. The flatter ones collect dust on their flat surfaces, so ideally they would be brushed with the DRT (Dust Removal Tool) before we analyze them, but they are often too fragile-looking, and we worry that some of the layers might break off or flake off. The amorphous ones have irregular surfaces, which can collect sand and dust and make getting a good placement tricky.

However, today we were able to get both APXS and MAHLI on the flattest, most dust-free looking patch at “Cerro Negro.” We will be able to compare the composition of the darker patches and the Garlock Fault vein, and hopefully tease out their relationship.

Mastcam will take a small mosaic of Garlock Fault and then a larger mosaic on crosscutting veins at “Wildwood Canyon.” This was previously imaged, but from a different angle, so getting a second image will allow us to calculate the orientations on the fractures. Further afield, the “Forest Falls” mosaic looks at an area of dark, raised vein material.

Looking at the drive direction image, the sedimentologists were very excited to see what appear to be ripple features in the rocks ahead of us, which can tell us a lot about the depositional environment. The Mastcam mosaic “Hahamongna” will image the outcrop we are driving towards (about 30 meters from today’s workspace, or 98 feet), to give context for what we see when we get there. Mastcam will take a second smaller mosaic at “Malibu Creek” midway between where we are today and where we hope to be on Wednesday.

Looking even further into our future driving path, we will obtain Mastcam and ChemCam RMI images of the top of Mount Sharp and the yardang unit. We have a bit to go before we get there of course, but we will use those images to examine structural relationships and consider the evolution of both — we can test all those theories when we get there!

We round out the plan with environmental monitoring, as always …and wait eagerly for the next workspace on Wednesday, when we will get up close to those ripples, with luck!

Written by Catherine O’Connell-Cooper, Planetary Geologist at University of New Brunswick

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