Webb Detects Tiny Quartz Crystals in the Clouds of a Hot Gas Giant

Webb Detects Tiny Quartz Crystals in the Clouds of a Hot Gas Giant

Researchers using NASA’s James Webb Space Telescope have detected evidence for quartz nanocrystals in the high-altitude clouds of WASP-17 b, a hot Jupiter exoplanet 1,300 light-years from Earth. The detection, which was uniquely possible with MIRI (Webb’s Mid-Infrared Instrument), marks the first time that silica (SiO2) particles have been spotted in an exoplanet atmosphere.

Illustration showing a portion of the disk of a cloudy planet set against the black background of space. About one-eighth of the planet is visible. It fills the lower right half of the frame, with the limb (the edge, or horizon) curving from the bottom left corner to the upper right corner. The planet is partially lit by a star that is off to the upper left, out of view. The planet is brightest along the limb (on the dayside), and grows dimmer toward the lower right corner (the nightside), becoming almost completely dark about halfway in. Wispy, light-tan-colored clouds are visible in the lit portion and there is a hazy blueish glow along the horizon. Several stars are scattered in the background.
This artist concept shows what the exoplanet WASP-17 b could look like.
Graphics: NASA, ESA, CSA, and R. Crawfor, d (STScI)Science: Nikole Lewis (Cornell University), David Grant (University of Bristol), Hannah Wakeford (University of Bristol) Crawford (STScI)

“We were thrilled!” said David Grant, a researcher at the University of Bristol in the UK and first author on a paper being published today in the Astrophysical Journal Letters. “We knew from Hubble observations that there must be aerosols—tiny particles making up clouds or haze—in WASP-17 b’s atmosphere, but we didn’t expect them to be made of quartz.”

Silicates (minerals rich in silicon and oxygen) make up the bulk of Earth and the Moon as well as other rocky objects in our solar system, and are extremely common across the galaxy. But the silicate grains previously detected in the atmospheres of exoplanets and brown dwarfs appear to be made of magnesium-rich silicates like olivine and pyroxene, not quartz alone – which is pure SiO2.

The result from this team, which also includes researchers from NASA’s Ames Research Center and NASA’s Goddard Space Flight Center, puts a new spin on our understanding of how exoplanet clouds form and evolve. “We fully expected to see magnesium silicates,” said co-author Hannah Wakeford, also from the University of Bristol. “But what we’re seeing instead are likely the building blocks of those, the tiny ‘seed’ particles needed to form the larger silicate grains we detect in cooler exoplanets and brown dwarfs.”

Detecting Subtle Variations

With a volume more than seven times that of Jupiter and a mass less than one-half Jupiter, WASP-17 b is one of the largest and puffiest known exoplanets. This, along with its short orbital period of just 3.7 Earth-days, makes the planet ideal for transmission spectroscopy : a technique that involves measuring the filtering and scattering effects of a planet’s atmosphere on starlight.

Webb observed the WASP-17 system for nearly 10 hours, collecting more than 1,275 brightness measurements of 5- to 12-micron mid-infrared light as the planet crossed its star. By subtracting the brightness of individual wavelengths of light that reached the telescope when the planet was in front of the star from those of the star on its own, the team was able to calculate the amount of each wavelength blocked by the planet’s atmosphere.

What emerged was an unexpected “bump” at 8.6 microns, a feature that would not be expected if the clouds were made of magnesium silicates or other possible high temperature aerosols like aluminum oxide, but which makes perfect sense if they are made of quartz.

alt="Graphic titled “Hot Gas Giant Exoplanet WASP-17 b Composition of Cloud Particles, MIRI Low-Resolution Time-Series Spectroscopy” showing 28 data points plotted as white circles with vertical error bars on a graph of amount of light blocked in percent on the y-axis versus wavelength of light in microns on the x-axis. The y-axis ranges from 1.45 to 1.65 percent. The x-axis ranges from 5 to 12 microns. A jagged purple line is labeled “Model spectrum based on Webb, Hubble, and Spitzer data.” One broad, prominent peak visible in the data and model is highlighted with a vertical green band labeled “Light blocked by quartz (S I O 2) crystals.” The peak is centered at about 8.6 microns and 1.59 percent. Running across the green band below the purple peak, is a jagged dashed yellow line labeled “What the spectrum would look like with no quartz clouds.” This line slopes down to the right. In the background is an illustration of a planet with wispy clouds and a hazy blueish glow along the horizon."
A transmission spectrum of the hot gas giant exoplanet WASP-17 b captured by Webb’s Mid-Infrared Instrument (MIRI) on March 12-13, 2023, reveals the first evidence for quartz (crystalline silica, SiO2) in the clouds of an exoplanet.
The spectrum was made by measuring the change in brightness of 28 wavelength-bands of mid-infrared light as the planet transited the star. Webb observed the WASP-17 system using MIRI’s low-resolution spectrograph for nearly 10 hours, collecting more than 1,275 measurements before, during, and after the transit.
For each wavelength, the amount of light blocked by the planet’s atmosphere (white circles) was calculated by subtracting the amount that made it through the atmosphere from the amount originally emitted by the star.
The solid purple line is a best-fit model to the Webb (MIRI), Hubble, and Spitzer data. (The Hubble and Spitzer data cover wavelengths from 0.34 to 4.5 microns and are not shown on the graph.) The spectrum shows a clear feature around 8.6 microns, which astronomers think is caused by silica particles absorbing some of the starlight passing through the atmosphere.
The dashed yellow line shows what that part of the transmission spectrum would look like if the clouds in WASP-17 b’s atmosphere did not contain SiO2.
This marks the first time that SiO2 has been identified in an exoplanet, and the first time any specific cloud species has been identified in a transiting exoplanet.
Graphics: NASA, ESA, CSA, and R. Crawfor, d (STScI)Science: Nikole Lewis (Cornell University), David Grant (University of Bristol), Hannah Wakeford (University of Bristol) Crawford (STScI)

Download full resolution images for this article from the Space Telescope Science Institute (STScI)

Crystals, Clouds, and Winds

While these crystals are probably similar in shape to the pointy hexagonal prisms found in geodes and gem shops on Earth, each one is only about 10 nanometers across—one-millionth of one centimeter.

“Hubble data actually played a key role in constraining the size of these particles,” explained co-author Nikole Lewis of Cornell University, who leads the Webb Guaranteed Time Observation (GTO) program designed to help build a three-dimensional view of a hot Jupiter atmosphere. “We know there is silica from Webb’s MIRI data alone, but we needed the visible and near-infrared observations from Hubble for context, to figure out how large the crystals are.”

Unlike mineral particles found in clouds on Earth, the quartz crystals detected in the clouds of WASP-17 b are not swept up from a rocky surface. Instead, they originate in the atmosphere itself. “WASP-17 b is extremely hot—around 1,500 degrees Celsius (2,700°F)—and the pressure where they form high in the atmosphere is only about one-thousandth of what we experience on Earth’s surface,” explained Grant. “In these conditions, solid crystals can form directly from gas, without going through a liquid phase first.”

Understanding what the clouds are made of is crucial for understanding the planet as a whole. Hot Jupiters like WASP-17 b are made primarily of hydrogen and helium, with small amounts of other gases like water vapor (H2O) and carbon dioxide (CO2). “If we only consider the oxygen that is in these gases, and neglect to include all of the oxygen locked up in minerals like quartz (SiO2), we will significantly underestimate the total abundance,” explained Wakeford. “These beautiful silica crystals tell us about the inventory of different materials and how they all come together to shape the environment of this planet.”

Exactly how much quartz there is, and how pervasive the clouds are, is hard to determine. “The clouds are likely present along the day/night transition (the terminator), which is the region that our observations probe,” said Grant. Given that the planet is tidally locked with a very hot day side and cooler night side, it is likely that the clouds circulate around the planet, but vaporize when they reach the hotter day side. “The winds could be moving these tiny glassy particles around at thousands of miles per hour.”

WASP-17 b is one of three planets targeted by the JWST-Telescope Scientist Team’s Deep Reconnaissance of Exoplanet Atmospheres using Multi-instrument Spectroscopy (DREAMS) investigations, which are designed to gather a comprehensive set of observations of one representative from each key class of exoplanets: a hot Jupiter, a warm Neptune, and a temperate rocky planet. The MIRI observations of hot Jupiter WASP-17 b were made as part of GTO program 1353.

The James Webb Space Telescope is the world’s premier space science observatory. Webb is solving mysteries in our solar system, looking beyond to distant worlds around other stars, and probing the mysterious structures and origins of our universe and our place in it. Webb is an international program led by NASA with its partners, ESA (European Space Agency) and the Canadian Space Agency.

Media Contacts:

Laura Betz
NASA’s Goddard Space Flight Center, Greenbelt, Md.
laura.e.betz@nasa.gov

Christine Pulliam
Space Telescope Science Institute, Baltimore, Md.
cpulliam@stsci.edu

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steve sabia

October Retirements

October Retirements

1 min read

October Retirements

Mark Hyatt

Portrait of Mark Hyatt.
Flight System Assurance Office, retired Sept. 30, 2023, with 38 years of NASA service.  
Credit: NASA

Mark David KanKam

Photo of Mark Kankam.
Office of STEM Engagement, retired Sept. 22, 2023, with 33 years of NASA service.
Credit: NASA

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Kelly M. Matter

COPV Standards

COPV Standards

Our COPV team evaluates new emerging technologies for custom applications.
Credits: NASA WSTF

Through collaboration with other government agencies, U.S. national consensus organizations, and international governments, our engineers have developed nondestructive evaluation (NDE) standards for composites through  ASTM International.

Along with being lead supporters of NDE standards development through the NASA NDE Development Program, our team has pioneered many pressure vessel testing methods accepted by the American Institute of Aeronautics and Astronautics (AIAA) as standard practice and we continue to work closely with  AIAA to maintain several standards of COPV design, testing, and certification. 

In addition to our facilities’ contribution to standards development, our engineers have extensive experience with applicable  NASA and ISO standards that apply to COPVs.

American Institute of Aeronautics and Astronautics (AIAA)

  • Space Systems—Metallic Pressure Vessels, Pressurized Structures, and Pressure Components (ANSI/AIAA S-080A-2018)
    • This standard lays the foundational requirements for design, analysis, fabrication, and operation of various pressurized components. Additionally, the standard outlines requirements for maintaining several types of pressure vessels and pressurized structures and components (AIAA 2018)…Learn more
  • Space Systems—Composite Overwrapped Pressure Vessels (ANSI/AIAA S-081B-2018)
    • This standard covers foundational requirements for composite overwrapped pressure vessels (COPVs) fabricated with metal liners and carbon fiber/polymer overwrap. The standard includes requirements for COPV design, analysis, fabrication, test, inspection, operation, and maintenance (AIAA 2018)…Learn more
  • Space Systems—Non-Metallic Composite Overwrapped Pressure Vessels (In-Development)

ASTM International

  • Standard Practice for Shearography of Polymer Matrix Composites, Sandwich Core Materials and Filament-Wound Pressure Vessels in Aerospace Applications (ASTM E2581)
     
    • This ASTM standard (E2581) provides practices for shearography, which is used to measure strain, shearing, Poisson, bending, and torsional strains. Shearography proves useful during process design and optimization, and process control. Additionally, it can be used after manufacture and in-service inspections (ASTM 2019)…Learn more.
  • Acoustic Emissions Standard
    • Standard Practice for Examination of Gas-Filled Filament-Wound Composite Pressure Vessels Using Acoustic Emission (ASTM E2191)
      • With safety in mind, guidelines have been composed by Compressed Gas Association (CGA) and others to focus on inspections for natural gas vehicle (NGV) fuel containers. Acoustic Emission (AE) testing of Gas-Filled Filament-Wound Composite Pressure Vessels is an alternative method to the three-year visual examination which requires removal of the container from the vehicle (ASTM 2016)… Learn more.
    • Standard Practice for Acoustic Emission Examination of Plate-like and Flat Panel Composite Structures Used in Aerospace Applications (ASTM E2661)
      • Acoustic Emission (AE) examination of plate-like and flat panel composite structures proves useful in detecting micro-damage generation, new or existing flaws, and accumulation. Furthermore, AE examination assists in locating damage such as matrix cracking, fiber splitting, fiber breakage, fiber pull-out, debonding, and delamination (ASTM 2020)… Learn more.
    • Standard Practice for Acousto-Ultrasonic Assessment of Filament-Wound Pressure Vessels (ASTM E1736)
      • The Acousto-Ultrasonic (AU) method should be carefully considered for vessels that show no major defects and weaknesses. It is key to use other methods like immersion pulse-echo ultrasonics (Practice E1001) and AE (Practice E1067) to determine the existence of major flaws before starting with AU (ASTM 2015)… Learn more.
  • Eddy Current Standard
    • Standard Guide for Eddy Current Testing of Electrically Conducting Materials Using Conformable Sensor Arrays (ASTM E2884)
      • Using eddy current techniques are a nondestructive way to find and identify discontinuities in magnetic or nonmagnetic electrically conducting materials. Planar and non-planar material examination is possible with conformable eddy current sensor arrays, but requires appropriate fixtures like a sturdy support frame and foam to hold the sensor array close to the surface of the material being examined (ASTM 2017)… Learn more.
  • Strand Testing Standard
    • Standard Terminology for Composite Materials (ASTM D3878)
      • The standard defines general composite terminology appearing in other standards about composites, containing high‑modulus fibers (greater than 20 GPa (3 × 10 6 psi)) (ASTM 2020a)… Learn more.
    • Standard Test Method for Tensile Properties of Glass Fiber Strands, Yarns, and Rovings Used in Reinforced Plastics (ASTM D2343)
      • This test method not only aids in providing research and developmental data, but also provides value for determining tensile properties while providing a means for identifying and delineating materials for control and specification. The intended use of this method is to test resin-compatible sized glass fiber materials designed especially for use with plastics in general (ASTM 2017)…learn more.

NASA Standards

  • Structural Design and Test Factors of Safety for Space Flight Hardware (NASA-STD-5001)
    • This NASA Technical Standard establishes factors for structural design and test and service life factors used for spaceflight hardware development and verification. These factors help to ensure safe and quality structural designs and aid to reduce project costs and schedules by improving shared flight project design. These standards are considered minimum acceptable values (NASA 2014)…Learn more (NASA and contractor personnel only).

 ISO Standards

  • Space Systems — Fracture and Damage Control (ISO 21347)
    • A fracture control policy is being implemented on space systems to prevent premature structural failure as a result of crack or crack-like flaws for civil and military space vehicles, launch systems, and ground support equipment. Most procurement organizations consider fracture control a requisite safety-related requirement regarding human space flight systems. NASA and the European Space Agency (ESA) require fracture control for all payloads using the NASA Space Shuttle and all instruments and equipment used on the International Space Station (ISS) (ISO 2005)…Learn more.

Last Updated: Jan 13, 2021

Editor: Judy Corbett

National Aeronautics and Space Administration

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Jeffrey E. Brubaker

Laser Activity Board

Laser Activity Board

Next Generation Science Standards

Waves and their Applications in Technologies for Information Transfer (MS-PS4)

Grades 5-8. Students strengthen their understanding of the electromagnetic spectrum, specifically lasers and their applications, through a series of math, writing, and graphing challenges. This series of activities can be completed together or in parts.

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Jermaine Walker